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the rule of thumb for liquids is that liquids with polar molecules (water, vinegar) will mix with each other, and liquids with non-polar molecules (oil, grease, ) will mix with each other but they will not mix with each other.

soap is made up of long chain molecules which are polar at one end and non-polar at the other, so they bridge the gap and bond up with a water molecule at one end and an oil molecule at the other allowing the oil molecules to be washed away with the water.

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Q: What is the type of reaction of soap and water removing oil or fat from object?
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