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Any kind of material that is even colder than the cold air will heat up. Materials that will react with the air in exothermic reactions will also heat up. An example would be those little packages you can buy that have a bunch of finely ground iron powder that when you break the seal, the iron starts oxidizing - which is an exothermic reaction - and can do a nice job of warming up your hands or feet if you stick it in your gloves or boots for a while.

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Q: What kind of material heats up in cold air?
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