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Assuming the plastic just melts and doesn't undergo a chemical change through carbonization (i.e., you burn it), it shouldn't stick to any iron-based metal. "Sticking" is related to the smoothness of the surface of the mold. If you mold has a mirror finish, you should be able to simply peel the plastic off.

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Q: What kind of the plastic material does not stick to ferrous metal after melting?
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