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The process is absorption of a photon. When energy like this is added to the system, if enough is added, then an electron can be ejected from the atom. The relevant theory involved with this is called 'band-gap' theory. Electrons are Fermions and as such obey the Pauli exclusion principle. This demands that no two electrons can occupy the same quantum state. Energy is quantised and therefore electrons can only take distinct energy levels at each orbital around an atom. The orbitals close to the nucleus are most tightly bound which means they must be given a tremendous energy to leave the atom. But if all the available slots in a particular orbital are filled, then an electron bound to the atom must occupy the next orbital further out. When all but the outer shell is filled, the only place for an electron attached to the atom is in this outer shell. In some atoms these electrons can be given enough energy by a photon to leave the atom and they do so because there are no further orbitals to occupy. In Silicon, this band-gap is 1.1 electron-volts. The figure varies by material.

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Q: What property describes how much energy must be added to an atom to remove an outermost electron?
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