A near rhyme would be Pennsylvania; while the last three syllables do rhyme, the first does not exactly.
Pennsylvania?
Transylvania University is located in the state of Kentucky.
transylvania
Transylvania is a historically region of Romania.
Rhyming can be stretched, but there isn't one state that surely rhymes with "wall."
South Dakota is a US state which rhymes with North Dakota.
transylvania king
Delaware
Transylvania is in Romania.
Transylvania is populated from the paleolithic.
Transylvania is a Romanian province.
Transylvania still exists.