It's one of Glee's unreleased background songs.
No, from my research it appears that it was actually gwyneth paltrow who wrote it, Chris Martin's wife.
They starred in the two "Iron Man" movies, in which Robert Downey Jr. plays billionaire industrialist Tony Stark and Oscar-winner Gwyneth Paltrow appears as his executive assistant, Pepper Potts.
episode 42 :)
That depends, are you looking for when she first appears? Or when she is first named in the series? She makes her first appearance in the background of Twilight Sparkle's party in Episode 1 (The Mare in the Moon) but only has an actual role in the second season. She appears briefly (with a speaking role) in Season 2 Episode 14 (The Last Roundup).
Episode 6
He appears in the second episode towards the end.
Pluto first appears in episode 7.
She first appears in the episode entitled "Rose" which is the first episode of the new series, episode 1.1.
It appears in episode 10, Madame Blueberry.
The episode was Canada on strike and songs name is what what in the butt, This was episode 12-4 and he doesn't take it in the butt he just sings the "what what in the butt" song
She Appears in episode 39 of sonic x near the end of the episode.
The Target Appears episode 97 of Naruto Shippuden