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You can use the ideal gas law to find the volume:

PV = nRT

V = nRT/P (use R=0.08206 L*atm/mol*K)

= (4.0 mol)*(0.08206 L*atm/mol*K)*(300K)/(2.0 atm)

V = 49.24 L

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Q: What volume will 4.0 mol of helium gas occupy at 300 K and 2.0 ATM?
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