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Concentration of products would increase in order to attain equilibrium in the system again.

For example:

H2CO3 --> H+ + HCO3-

K= ([H+][žHCO3-])/([H2CO3])

K is constant for this process, so if you increase the concentration of reactants (H2CO3), in order for K to stay the same, concentration of products (H+, HCO3-) would also have to increase.

It's part of Le Chatelier's principle: "If a chemical system at equilibrium experiences a change in concentration, temperature, volume, or partial pressure, then the equilibrium shifts to counteract the imposed change and a new equilibrium is established."

So, in your case, adding more reactant would cause equilibrium to shift to the right (toward products), and therefore, their concentration would increase so that new equilibrium could be established.

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Gillian Watsica

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Q: What would happen to a weak acid dissociation if more reactants were added?
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