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Temperature of a solution is a condition that controls the solubility of solute in a solvent. Take copper sulfate for example. At 100° Celsius (C) 203.3 grams (g) can be dissolved in 100ml of water; at 0° C, only 31.6g can be dissolved in water.

If you continue to boil the solvent (water) away, the copper sulfate will come out of solution because the amount of water is lessened creating a supersaturated state that forces the solute out of the solution (in other words, the lesser amount of liquid water can't hold that much copper sulfate in solution.) Removing the heat source and allowing the solution to cool has the same effect. As it cools,the copper sulfate will come out of solution.

So, basically, concentration of the solute at a given temperature is the controlling factor. Boiling off the solvent increases the concentration; cooling the solvent decreases the concentration the solvent can hold. Both ways create a state of supersaturation leading to crystallization at all the temperatures in the given range.

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