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They were never invented.

They were discovered by various people at various times:

Ernest Rutherford effectively discovered protons, around 1910, with his famous gold film experiment. He is usually "officially" credited with the discovery for his work in 1919.

The electron was discovered in 1897 by J.J. Thomson.

The neutron was discovered in 1932 by James Chadwick.

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Q: When electron neutron and proton were invented?
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