Big Helium Dog was created in 1999.
Big Dog Motorcycles was created in 1994.
The Big Stuffed Dog was created in 1981.
Big Black Dog was created in 1970.
Big Dog Daddy was created on 2007-06-12.
The matter that came out of the Big Bang was about 90% hydrogen and 10% helium.
The big bang produced the helium no present in the sun's core. The universe cooled down enough after the big bang to form the formation of helium and hydrogen.
Boston Dynamics
It wasn't. Right after the Big Bang, there was only hydrogen (including deuterium), helium, and minute amounts of lithium. Apart from that, all the so-called metals - i.e., elements other than hydrogen or helium - were created in supernovae.
Helium is the 2nd lightest element and is the 2nd most abundant in the Universe. Most helium was formed during the Big Bang (See Link), but new helium is being created as a result of the nuclear fusion of hydrogen in stars.
Mt. Helium was created in 1999.
National Helium Reserve was created in 1925.
Norman Bridwell's creation Clifford the big Red Dog's first appearance was in the 1963 book Clifford, the Big Red Dog.