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You can't catch then you can only have them by:

elekid:1.Get a boy electrabuzz and a girl and leave them both at the daycare granny.

2.Do Lots of stuff and then go back at the daycare and talk to the old man infront of the daycare(husband) of daycare lady).

3.Make sure to have one Pokemon slot and there you have it an egg,but still you have to hatch it an there you have it an elekid

electrizer option1: You need to have an electrabuzz and try only fight with him or her.

option2:You can put electrabuzz the Rep.XP and fight with the strongest Pokemon you have, I recommend Lv.100.

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