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Comes from greek word 'pinax'
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∙ 12y ago
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What is pinacol?
Pinacol is the common name for a dihydric alcohol having I.U.P.A.C. name 2,3-dimethyl-2,3-butadiol
What is the synthesis of pinacol and pinacolone?
This reaction was first described by Wilhelm Rudolph Fitting in 1860. the pinacol rearrangement or pinacolone rearrangement is a method for converting a 1,2-diol to a carbanyly compound in a organic chemistry. This 1,2 rearrangement take place under acidi condition. the name reaction come from the rearrangement of pinacol to pinacolone.
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Scope of pinacol rearrangment in organic synthesis?
I don't really understand your question but pinacol (a diol) rearranges itself to form a carbonyl compound under acidic conditions. One of the OH groups becomes protonated and leaves as H2O forming a tertiary carbocation. A methyl group migrates over to the carbocation leaving a positive charge on the carbon with the remaining OH group. One of the lone pairs on the oxygen forms a double bond with the carbon. The proton on the oxygen then leaves to form a carbonyl compound called pinacolone. Check this out for more info. http://en.wikipedia.org/wiki/Pinacol_rearrangement
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