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Burn Lv5 doesn't exist in the original Pokemon Ranger.In Shadows of Almia, Magmortar has Burn Lv5Though I don't know where they are...
The statue in Almia Castle, where Mismagius is. You need to use 5 burn on the statue.
The ONLY Pokemon with level 5 burn is magmortar, which you can find in boylelands volcano. Use your browser next time :)
Garchomp
garchomp in hippowdon temple
Yes there is... its Ramparados and it can be found at Peril Cliffs
Zubat has Pokemon assist 5.
Go into the hippowdon temple should find a Garachomp 5 crush.
#265: REGICE Group: Ice Poké Assist: Ice Field Move: None Area: Almia Castle Required Field Move(s): 1x Burn 5 It is in the Mismagius Room
rampardos, it can be found where the "geologist" used 2 of them in peril cliffs- ony one i there though
rock: union road before waterfall required: crush lv.5 ice: almia castle in mismagius's room required burn lv. 5 steel: chroma ruins near shadow altar requierd: gallade rock: union road before waterfall required: crush lv.5 ice: almia castle in mismagius's room required burn lv. 5 steel: chroma ruins near shadow altar requierd: gallade
Capture Gallade in the Altru Tower after you defeat it as a boss.