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Q: Which Department of Transportation Special Permit applies when shipping NSN 1410-01-235-7044 NALC PC84 material by motor vehicle?
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What does the federal motor carrier safety administration oversee?

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Does shipping companies have any special instructions to deliver alkali metals?

When shipping hazardous materials such as these, the box must be labeled as to what it contains, and ususally a code to potential hazards, and accompanied by a MSDS sheet (Material Safety Data Sheet, which tells hazards of the material, cleanup procedures, and other information). Most carriers require that the shipper be licensed (with the carrier) to ship that particular hazardous material. Some carriers may have an exemption for the license requirement if shipping small quantities. Some limitations are imposed by the Department of Transportation, but the carrier can have more restrictive requirements. Check with the carrier that you are thinking about using (for example fedex.com or ups.com or usps.com) and do a search for hazardous material, or maybe even the specific item that you are interested in.