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You might be referring to the metals whose oxides are amphoteric-can behave either as acids or bases. There are many of these, including zinc and aluminum.

For more about this subject see the wikipedia article about amphoterism.

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Q: Which Metal oxide is acidic in nature?
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It is electronegetive in nature and so it can be called acidic.


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Nitric oxide is acidic in nature.


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A metallic oxide is basic in nature.


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Nitrogendioxide


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