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The question as to which social networks offer chatting services for free is a rhetorical question, as chatting is exactly the basic principal of social networking. This would mean that any site that is known as a social networking site offers just exactly that service.
There is none.
One of the most popular online chatting websites is Facebook. Another popular chatting website, one that uses webcams to connect the users, is ChatRoulette.
Usually 13.
There are many great chat room websites available for free. The best ones are Chatablance.com, Chatroulette.com, Chatforfree.org and customvideochat.com for video chatting.
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Google 'Chat Room Sites' yielded about 30,400,000 results.
One can find chat rooms for singles online at various websites. One can find chat rooms for singles at websites such as Free Chat Now and Chat Connection.
There are many websites with services that offer chatting to live girls through video or over the phone. Some services, such as Omegle or Chat Roulette, are free, but run the chance of ending up talking to a guy instead of a girl.
There are many websites with which one can chat with strangers. Two of these are Chatroulette (which offers video chatting), and Omegle (which overs both text and video chatting).