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Great Britain
The British Empire that had evolved by AD 1900 was racked with internal problems. Though the empire reached its industrial peak, poverty continued to be a major problem.
The Kingdom of Great Britain had the largest empire of any other Western European country, as well as any other country in the world, during 1900.
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BritainSpain had by far the largest Empire.
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The largest country in the world is currently the Russian Federation, laregely because they control all of Siberia. The largest country in history would be the British Empire, the Mongol Empire, or the Soviet Union, depending on your definition of a country.
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Austria-Hungary
BRITAIN had the largest global empire, both in territory and in population.
It was the largest empire in West Africa and Africa.