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The most acidic is HI with a pKa of -9.5, followed by Hbr then HCl and the least acidic is HF with a pKa of 3.18. The reason is that F is so electronegative it is highly hydrogen bonded. Dilute solutions are weakly acidic.

The iodide ion is the largest of all the halides (Astatine excluded because of its rarity and radioactivity) which results in the negative charge being delocalized over a larger volume of space.

The chloride ion is significantly smaller, meaning its negative charge is more concentrated in a smaller volume of space, leading to a stronger interaction between the proton and the chloride ion. This weaker H+ ---> I- interaction in HI facilitates dissociation of the proton from the anion, and is the reason HI is the strongest acid of the hydrohalides except for hydrohalide formed from Astatine- in theory.

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Q: Which has the least degree of acidity among HI HCl Hbr and HF and why?
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