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liquid oxygen is in effect more explosive than tnt, but by means they are different. liquid oxygen is not explosive at all without the other chemicals, where all tnt needs is heat, making tnt easier to use. also, one must the fact that tnt is more practical in that it is easier to come by. so, if you put the same effort into aquiring them both, you would end up with enough tnt to make a larger explosion than the one made by the amount of liquid oxygen you would aquire.

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Q: Which is more explosive TNT or Liquid oxygen?
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