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The 4 state of matter is Plasma. Plasma require very large quantities of energy to be produced as it's a free flowing 'soup' of delocalised electrons and positivity charged nuclei. A ionised gas such are the ones in fluorescent bulbs is an example of a plasma

The 5th state of matter as declared by Einstein is the Bose-Einstein condensate which only occurs at tempuratres very close to absolute zero which aren't found naturally. In this state matter stops behaving as particles and collapses into a single quantum state.

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