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The only thing I can think of is the size match between Cl and the B or Al; there's more likely to be an interaction between the vacant AO on Al than B and the Cl lone pairs because the AOs are better matched in energy and size, making the bonding interaction more favourable.

I might be talking rubbish but that's one theory anyway!

A.P.

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Q: Why BCL3 is monomer but BH3 exists as Dimer?
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Related questions

What is the chemical formula of boron and hydrogen?

BH3. but the compound generally exists as its dimer B2H6.


What is the name of the covalent compound BH?

BH is not stable, there is no compound by that formula. BH3 (boron hydride) generally exists as the dimer, B2H6, diborane.


How do you write a formula for the compound of boron chloride?

Formula: BCl3


Bh3 can't exist but bx3 can exist why?

BH3 is a electron deficient molecule it fights for the attention of all electrons therefore creating a dimmer molecule. A dimmer in scientific terms is considered non existent.


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The predicted boiling point for borane is 440,34 oc.


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Increasing order of Lewis acidity BH3>BBR3>BCl3>BF3


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5,00 g of BH3 is equal to 0,36 moles.


Why bh3 polymerizes but not ch4?

because ch4 has an octett and bh3 not so it dimerises to b2h6


How many grams are in 6.3 moles of BH3?

6.3(mol) * 13.83 (g·mol−1)= 87.1 gram BH3


What does boron and hydrogen make?

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Does the Lewis structure of BH3 contain an atom that does not obey the octet rule?

BH3 does not obey octet rule.it has a total of six electrons only.boron has three electrons in the valence shell and it accepts one electron from each hydrogenBH3 is a planar molecule and is found only in the gaseous state.BH3 dimerises to form B2H6 with 4 terminal hydrogens attached by normal covalent bonds and 2 hydrogen bridges , 3 centre 2 electron bonds. Once again in the dimer it does not obey the octet rule.


Chemical formula of boron trihydride?

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