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B forms 3 bonds (has 3 valence electrons) and is sp2 hybridized, so the molecule is trigonal planar, which is symmetrical. P can form 5 bonds (has 5 valence electrons), and in PCl3 has a free electron pair which makes the molecule non-symmetrical.

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13y ago
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13y ago

The geometry of PCl3 is trigonal pyramidal. As a result the more electronegative chlorine atoms pull the electrons away from the phosphorus in a net direction.

The geometry of BCl3 is trigonal planar. So the three B-Cl bonds are evenly spaced in the same plane. As a result, the polarity of the bonds essentially cancel each other out.

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Q: Why PCl3 has a dipole moment and BCl3 does not have a dipole moment?
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