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The light blue color of a solution of CuSO4 in water is due to absorption of yellow light by a coordination complex of water and copper cations. When NH3 is added, the water molecules in the coordination complex are replaced by ammonia molecules, and the resulting complex absorbs yellow light more strongly than the original one.

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13y ago
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1w ago

The addition of NH3 to a blue CuSO4 solution forms a complex ion called [Cu(NH3)4]2+ which has a deeper blue color. This complex ion results from the ammonia molecules replacing water molecules around the copper ion in the solution, causing a shift in color.

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Q: Why The blue CuSO4 solution turn to a still deeper blue When NH3 is added?
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