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All aldehydes give a positive result with Fehling's test. All ketones give negative results.
I think you are referring to the test using Fehlings solution. Fehlings solution oxidises aldehydes and ketones and formic acid and is in turn reduced. The red precipitate is the copper(I) oxide formed by reduction of the copper(II) complex found in Fehlings solution. Acetic acid is not readily oxidised and so there is no precipitate. See link for more information on what the complex is in Fehlings solution and how it is prepared.
Aldehydes and ketones haven't an -OH group.
No, monomers and polymers of aldehydes and ketones do not have hydroxyl groups attached. Aldehydes and ketones have a carbonyl group (C=O) attached to at least one carbon atom and do not have any hydroxyl groups (-OH) attached to the carbon chain.
bORSCH REAGENT ALSO CALLED bRADY REAGENT .iT IS USED TO DETCT ALDEHYDES AND KETONES
ketones and aldehydes
All aldehydes give a positive result with Fehling's test. All ketones give negative results.
The aldehydes and ketones having three or less carbon atoms are soluble in water.
alcohol
I think you are referring to the test using Fehlings solution. Fehlings solution oxidises aldehydes and ketones and formic acid and is in turn reduced. The red precipitate is the copper(I) oxide formed by reduction of the copper(II) complex found in Fehlings solution. Acetic acid is not readily oxidised and so there is no precipitate. See link for more information on what the complex is in Fehlings solution and how it is prepared.
Aldehydes and ketones
Aldehydes are less sterically hindered than ketones. Also, aldehydes have fewer electron donating groups (EDG's) which can stabilize an electron-poor area. The extra carbon chain that ketones have that aldehydes do not have are the reason for both of these things. The neighboring carbon to the carbonyl carbon is an EDG and the carbon chain causes steric hindrance.
Only aldehydes give a positive Tollens test. However, under the strongly basic conditions of the test, alpha-hydroxy ketones can isomerize to aldehydes, so they will also give a positive Tollens test. Fructose is an alpha-hydroxy ketone.
The principle of Tollens' test is to distinguish between aldehydes and ketones. It involves the reduction of silver ions to silver metal in the presence of aldehydes, which results in the formation of a silver mirror on the inner surface of the test tube. Ketones do not give a positive Tollens' test because they do not undergo this reaction with silver ions.
Ketones or Aldehydes DO NOT react with Sodium Bicarbonate..generally only Carboxilic acids have the ability to do it!
alcohols, aldehydes or ketones, or carboxylic acids
Aldehydes and ketones haven't an -OH group.