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Benzyl chloride reacts faster than 1-chlorobutane because of its Benzylic system.

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15y ago
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4d ago

Benzyl chloride reacts faster than 1-chlorobutane with sodium iodide in acetone due to the stability of the benzylic carbocation intermediate formed in the reaction, which facilitates nucleophilic attack by iodide. The resonance stabilization of the benzyl carbocation makes it more reactive compared to the primary alkyl carbocation formed in the case of 1-chlorobutane.

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Q: Why benzyl chloride reacts faster than 1-clorobutane when treated with sodium iodide in acetone?
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