Want this question answered?
Titrate each solution separately with solution of known concentration of sodium thiosulphate. The titre value will give the amount of thiosulphate reacted with iodine, hence you can find concentration of iodine.
· In analytical chemistry, sodium thiosulphate is used for the determination of the strength of a given solution of iodine. · Sodium thiosulphate is preferred in iodometric analysis due to the fact that sodium thiosulphate is oxidized by iodine. It is also used to determine the strength of many oxidizing agents.
Brown/Orange/Yellowy
negative
The Iodine test uses Iodine solution, which is usually a brown colour. It is used to test for the presence of Starch. Iodine solution, iodine dissolved in an aqueous solution of potassium iodide, reacts with starch producing a blue black color. If the sample being tested doesn't turn blue-black, then starch isn't present.
Titrate each solution separately with solution of known concentration of sodium thiosulphate. The titre value will give the amount of thiosulphate reacted with iodine, hence you can find concentration of iodine.
· In analytical chemistry, sodium thiosulphate is used for the determination of the strength of a given solution of iodine. · Sodium thiosulphate is preferred in iodometric analysis due to the fact that sodium thiosulphate is oxidized by iodine. It is also used to determine the strength of many oxidizing agents.
In iodometry sodium thiosulphate is used because it is standardized by potassium dichromate and it is the best and relaible way to standardized sodium thiosulphate using iodometric titration. Infact sodium thiosulphate is also standardized by iodimetry. The difference between both of them is only of iodine. In iodometry iodine gas is liberated that will further react with sodium thiosulphate but in iodimetry standard solution of iodine is used.
Brown/Orange/Yellowy
cause iodine(brown) stains the rice
This reaction may be misunderstood as a direct reaction between the thiosulphate and iodate ions , however, in practice an iodide and acid mediated production of iodine from the iodate is used to react with the thiosulphate. A standard reaction used to calibrate a solution of sodium thiosulphate is as follows: Acid and potassium iodide are added to a solution of potassium iodate getting the following reaction: KIO3 + 5KI + 3H2SO4 = 3I2 + 3K2SO4 + 3H2O represented by the following ionic equation: IO3- + 5I- + 6H+ = 3I2 + 3H2O Thiosulpathe is titrated against this solution (effectively against iodine): I2 + 2Na2S2O3 = Na2S4O6 + 2NaI represented by the following ionic equation: I2 + 2S2O32- = S4O62- + 2I- where the dark brown coloured solution of iodine turns pale yellow and finally colourless as the reaction proceeds (starch is used as indicator after the pale yellow transition forming a black solution due to an iodine-starch complex which turns colourless upon further addition of thiosulphate).
Iodine Value of Activated Carbon Apparatus: Volumetric flask, conical flask, beaker, burette, pipette, filter paper Reagents: * 0.1N Iodine solution ( 40 gm KI in 1 Ltr of Distilled water ). * 0.05N Sodium Thiosulphate solution (12.5 gm Na2S2O3.5H2O in 1 Ltr Distilled water) * 1% Starch solution * Activated carbon Procedure: I Standardisation of Iodine solution * Take 10c.c of 0.1N Iodine solution in conical flask. * Add 2 drops of Starch solution. * The pale yellow colour of Iodine Soln turns Blue. * Titrate with 0.05 N Sodium Thiosulphate till it becomes Colourless. * Burette reading corresponds to blank reading.(B) II * Weigh very accurately 0.2 gm of Activated carbon * Introduce it into the Iodine flask which should be completely dry * Add 40cc of 0.1N Iodine solution * Shake the flask for 4 minutes and filter it * Collect the filterate in a dry flask and Titrate 10cc of the filtrate against Standard Sodium thiosulphate solution using starch as indicator * Burette reading corresponds to (A) Calculations: Iodine value: C x Conversion factor; mg/gm Factor:Mol wt. of iodine (127) x normality of iodine x 40 / Wt. of carbon x Blank reading C=B-A This is dry basis test From Ishan Udyog Bhilai
It turns a dark purple/blue colour
The iodine produced from the KIO3 reacts with the starch to produce the blue black colour used as the indicator
it is a yellowish/orange colour but when iodine is present, than it will turn an dark-blue/black colour
iodine solution
starch will not change its own colour but it can change the colour of iodine solution. iodine solution is originally brown. after adding starch, it will turn into dark blue.