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Because then, instead of a small volume of relatively concentrated radioactive material, what you get is a large volume of dilute radioactive material that you don't know the exact location of, which may still include relatively concentrated pockets. Dispersion is pretty much exactly what you do notwant to happen with radioactive waste, unless you can precisely control the dispersion and make sure that the concentration is everywhere negligible.

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Q: Why can't spent nuclear fuel rods be deposited in magma flows to dispense the radioactive material?
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