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Alkali metal atoms can often be substituted by other atoms under the right conditions

An example is Caesium in Caesium Chloride. By heating Caesium chloride with Calcium metal, caesium is substituted by calcium and the caesium can be distilled off at about 700oC under vacuum. This seems surprising, particularly given the higher reactivity of caesium, but the greater lattice energy of calcium chloride makes this the energetically preferred product over caesium chloride and drives the reaction.

(As an aside, this was the most terrifying reaction that I ever did in a lab because of the high temperature caesium that is produced...)

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Q: Why cant other alkali metals be substituted?
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