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For transporting water? Because lead will dissolve very slightly in water, and lead is fairly toxic. Copper is more durable, and doesn't dissolve.

The Romans used lead, which they called "plumbum", because lead is soft and malleable; you could pound the ceramic tiles into lead to get a watertight seal.

Please notice the Latin word for lead; "plumbum", from which we get the word "Plumbing" to mean water handling mechanisms.

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