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As you go from left to right on the Periodic Table, the atomic number increases, but the principal quantum number (number of shells present) does not. Therefore, as the nuclear charge increases, this increases the amount of energy required to remove an outermost electron (ionization energy).

However, as you go down the periodic table, the principal quantum number (number of shells) increases. As more and more shells of electrons are added between the outermost shell and the nucleus, these inner shells contribute a "shielding effect" to the outermost electrons, due to interelectron repulsion, which reduce the ionization energy of an atom, because it acts slightly in opposition to the nuclear charge attracting those electrons.

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Q: Why does ionization potential increase with an increase in atomic number in the period but decreases in a group?
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Related questions

Why does the ionization energy tend to decrease from top to bottom within a group?

there is an increase in atomic number and atomic size down the group due to addition of extra shells.this increase in the atomic size overcomes the effect of an increase in the nuclear charge.Therefore ionisation energy decreases with an increase in atomic size i.e.,it decreases as one moves down a group..


How can you determine whether ionization energy is a periodic function of atomic number?

as atomic number increases, ionization energy also decreases


How does the ionization energy vary with atomic number within the group?

Ionization energy decreases with the rise of atomic number in a group of periodic table.


What is the trend found in Period 3 on the Periodic Table as the elements increase in atomic number?

1-Atomic size = decreases 2-Ioniztion energy = increases 3-Electronegativity = increases (except Argon) 4-Metallic character = decreases 5-Melting point = first increases then decreases


What happens as we move down columns on the periodic table?

As you move down a column (group) in the periodic table, the electronegativity decreases, the ionization energy decreases, the electron affinity decreases, and the atomic radius increases.


What decreases with increasing atomic number in group 2a of the periodic table?

ionization energy


What happens when the nuclear charge increases across a period?

The atomic size decreases (with some exceptions) , the ionization energy , electronegativity and electron affinity also increase from left to right.


What is the correlation of ionization energies to atomic radii for the elements?

In a group the ionization energy decrease when the atomic radius increase; in a period this relation is not generally valid.


What is the Trend in first ionization energy across a period?

As one proceeds down the group 7A elements, the first ionization energy decreases. this means that the outermost electron is more readily removed as we go down a group.


An increase in the atomic number the atomic radius moving from left to right across a period.?

decreases


Why does atomic size increase from left to right across a period?

atomic size decreases across a period


What is the relationship between elements and the periodic table and ionisation energy?

The relationship between atomic numbers and first ionization energies is that within the same period, as atomic number increases so does first ionization because as nuclear charge increases and atomic radius decreases, electrons become harder to remove. However, within the same group, the first ionization energy decreases as atomic number increases because of the added energy level, the electrons are farther from the nucleus and easier to remove.