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P and S both have 'd' orbitals in outermost shell while N and O do not.

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Q: Why does phosphorus and sulfur expand octets in many of their compounds but nitrogen and oxygen never do?
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Elements in the third row of the periodic table or lower can have octets?

expanded


What is the electronic geometry of PO4-3?

Total valence electons = 26. Bonding electrons = 6. Place the Phosphorus in the center with the three Oxygens bonded to it. Use 20 (26-6) electrons to fill the octets of the oxygens... you have 2 electons left over to put on the phosphorus to fill its octet. 3 bonds plus 1 lone pair gives a steric number of 4. With one lone pair, the molecular geometry is trigonal pyramidal.


What is the formula for dinitrogen hexafluoride?

It doesn't exist. The valence shell of oxygen (n = 2) does not have access to any d orbitals, so oxygen is unable to expand its octet to produce OF6. However, the compounds sulfur hexafluoride (SF6) and selenium hexafluoride (SF6) do exist because they have access to d orbitals in which they can form expanded octets. The hybridization of the central atom in SF6 and SeF6 is sp3d2.


How many octets of electrons are in a Lewis structure?

The maximum number of electrons in a Lewis structure is eight, which is an octet of electrons.


What is the Lewis dot structure for H H?

The Lewis Dot Structure for Helium (He) is,* He :When Helium wants to bond with another atom, it is one of the three exceptions to the octet rule.*Ex. He:HeWhile most other elements have to bond with octets. Such as Hydrogen, Carbon, and Nitrogen.*H-C_=N:Hydrogen bonds once with Carbon and Nitrogen and Carbon have to make an octet so the three lines (_=) and the same as the dot structure (:::) The two valence electrons on the left side of the Nitrogen atom cannot join the Carbon and Nitrogen bond because there is no way two atoms can have a quadruple bond.Remember that each line equals to two electrons. So Nitrogen and Carbon have 8 electrons that they share, satisfying the octet rule.