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There is a greater repulsive force from the negatively charged anion, thus causing the addition of successive electrons to be electrically unfavorable. Energy is necessary to overcome the electrostatic repulsion, making additional electron affinities endothermic.

For the same reason, the noble gases and nitrogen absorb energy even for their first ionization energy. Greater stability = energy released. It requires energy to disrupt that stability.

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Q: Why is energy absorbed during successive electron affinities?
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