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Boiling this is done to remove ALL carbon dioxide (as gas) from the solution, before titrating the HCl-excess 'back' with titrant sodium hydroxide. Otherwise CO2 is disturbing the reaction at the end point of this backtitration at pH = 7 to 8 indicated by phenolphtaleine)

Na2CO3.xH2Oaq + 2HClaq --> 2NaClaq + H2Oliq + CO2(gas) + H+aq,(excess)

(Don't forget to cool down after boiling)

OH- + H+(excess) ==> H2O

OH- + CO2 |-o-| 'nill'

(= no reaction of CO2 to form HCO3-, which is formed at pH = 7 to 8)

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Q: Why is hydrated sodium carbonate and excess hydrochloric acid boiled when reacting together?
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