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This heat expandes the substance inside the can. Once the pressure is high enough the can will explode.

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Q: Why is it dangerous to leave an aerosol in direct sunlight?
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You should never throw an aerosol can onto a fire or leave it in direct sunlight - even if it is empty. This is because the pressure will build so up so much that the can will burst (and explode if there is a naked flame nearby). There are two reasons for the pressure going up:the gas pressure increasesmore of the liquefied propellant turns into a gas


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