answersLogoWhite

0


Best Answer

The second ionization energy of sodium is so much greater than the first because the first electron is removed from the valence shell, while the second electron is removed from the core orbitals. Additionally, the sodium atom has a positive charge after the first ionization, which thus attracts the remaining electrons more strongly. Both of these factors lead to a much higher second ionization energy compared to the first.

User Avatar

Wiki User

11y ago
This answer is:
User Avatar
More answers
User Avatar

Wiki User

11y ago

Let us define first what is ionization energy. It is the energy that is necessary to remove the outermost electron from an atom's subshell.

Moving from left to right across a period in the Periodic Table, the atomic number, and therefore the nuclear charge, of each increases. However, moving down a group in the periodic table, the increase in atomic number is "shielded" by the increasing number of electron shells surrounding the nucleus, consequently, the effective nuclear charge decreases.

In general, the greater the effective nuclear charge of an atom, the more closely the electrons are held, and consequently, the greater the ionization energy. So,

1) Moving from left to right across a period, the ionization energy increases (as the nuclear charge increases)

2) Moving down a group from top to bottom, the ionization energy decreases (as the effective nuclear charge decreases due to the shielding effect of the electrons)

Here's a quick trick: The closer an element is to Fluorine in the periodic table, the larger the element's value for ionization energy.

Therefore, Chlorine has a higher ionization energy than sodium since it is more closer to Fluorine. And as chlorine's nucleus has more protons than the nucleus of Na so its nucleus is more +ve than the nucleus of Na. They both have the same number of shells as well so the attraction between the chlorine's nucleus and its electrons is more than that between the sodium's nucleus and its electrons so more energy is needed to remove an electron from the chlorine atom.

Plus, the chlorine atom is slightly smaller than the sodium atom which also increases the ionisation energy.

Hope you are satisfied with the answer :) .

This answer is:
User Avatar

User Avatar

Wiki User

11y ago

Chlorine because the trend of ionization energies is up and to the right, both sodium and chlorine are in the third period but since chlorine is further to the right of the periodic table it has a higher ionization energy.

This answer is:
User Avatar

User Avatar

Wiki User

11y ago

Ionisation energy of elements increases across periods.

The ionisation energy of metals is the lowest as metal elements has a low electronegativity which means it tend to lose it's electrons easily.

Ionisation energy increases in such a trend :

Metals < Non-metals < Noble gases

Therefore comparing sodium ( Na ) and copper (Cu), Cu is more on the right side of the periodic table, causing it to have a high ionisation energy.

This answer is:
User Avatar

User Avatar

Wiki User

14y ago

Cl has a bigger nucleus, creating a stronger pull on electrons. (higher electronegativity)

This answer is:
User Avatar

User Avatar

Wiki User

11y ago

because chlorine has larger size than oxygen and ionization energy decreases with increase in size

This answer is:
User Avatar

Add your answer:

Earn +20 pts
Q: Does sodium or chlorine have a higher ionization energy?
Write your answer...
Submit
Still have questions?
magnify glass
imp
Related questions

Sodium an alkali metal and chlorine a halogen are both in Period 3 of the periodic table Which element has a higher ionization energy?

Chlorine has a higher ionization energy. Chlorine's tendency is to gain electrons, not lose them as metals usually do.


What elements has the greatest ionization energy Sodium Potassium Chlorine or Bromine?

chlorine (greatest), bromine, sodium, potassium (least)


Why is the ionistaion energy of magnesium higher than that of sodium?

because ionization energy increases from left to right on the periodic table. Ionization energy is the amount of energy needed to take an electron away from the atom, or the energy needed to ionize it. Since Sodium is more likely to give up an ion to complete the octet rule, it has a higher ionization energy.


Which statement describes the general trends in electronegativity and first ionization energy as the elements in Period 3 are considered in order from Na to Cl?

The Pauling electronegativity and the first ionization energy increase from sodium to chlorine.


The ionization energy for sodium is 496 kJmol The electron affinity for chlorine is -349 kJmol what is the enthalpy?

just add them together and you get 147kj


What is first ionization energy?

Sodium's first ionization energy is 495 kJ / mol.


What is the trend in ionization energy of Na Cl F?

The ionization energy increase from sodium to fluorine.


Which is more reactive sodium or barium?

sodium because it's the first group and first group are the most


What are the ionisation enthalpies of potassium and sodium?

First ionization energy of sodium is 495,8 kJ/mol.First ionization energy of potassium is 418,8 kJ/mol.


What are two examples of elements that undergo the prosses of ionization?

Sodium losses its electron to chlorine


Does sodium have a low or high ionization energy?

low


Does calcium have a lower first ionization energy level than sodium?

No. Calcium has TWO valence electrons, and Sodium has ONE. It is lot easier to take off one, than two you see. However, the second ionization energy of calcium IS however than the second ionization energy of Sodium. ;)