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Why is there a process of resonance?

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Anonymous

12y ago
Updated: 8/20/2019

Resonance in chemistry is a concept rather than a process. Two different wave functions are mixed to improve the fit between the calculated result and the observed. The wave functions are often shown as simple resonance forms (canonicals) which look like alternative Lewis structures for the molecule.

It was introduced initially by Heitler and London in their very early work on the H2 molecule where they "mixed" covalent and ionic structures in order to refine the calculation of bond strength. The concept was then used extensively by Pauling. It formed the basis for his description of electronegativity.

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12y ago

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