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Write a detailed set of equations for the acetylation reaction, and in particular show clearly that the reaction can be regarded as a nucleophilic substitution, in which the attacking nucleophile is aniline (attacking acetic anhydride).
Mineral oils don't contain aniline, but the aniline pointis a characteristic of oils (defining the content of aromatic hydrocarbons).
The aniline point of kerosene is 60-69 oC.
Aniline doesn't react with sodium hydroxide.
In o-aniline phenol Intramolecular hydrogen bonding occurs which is not possible in meta and is responsible for less solubility
Write a detailed set of equations for the acetylation reaction, and in particular show clearly that the reaction can be regarded as a nucleophilic substitution, in which the attacking nucleophile is aniline (attacking acetic anhydride).
An acetanilide is an amide derived from acetic acid and aniline, once used as an analgesic and antipyretic.
benzyl amine is the most basic
Acetic anhydride and aniline are the reactants for the preparation of acetaanilide.
Actually it is possible to put a second acyl group on as well, for example with acetyl chloride and triethylamine. Under aqueous basic conditions the second acyl group is far more readily hydrolysed.
Dyes are of several types they may be acidic , basic or neutral, organic dyes are mostly basic.
Strength of bases is related to the ease of accepting a proton which inturn depends on the availability of electron pair on the nitrogen atom (or some other basic atom). More is the availability of electron pair, more easily the proton will be accepted and more will be the basic strength.Aniline is a weaker base than ammonia or cyclohexylamine. It is because of the fact that the electron pair on nitrogen is involved in delocalization, making it less available for donation.
For acetanilide, resonance delocalization of the nitrogen lone pair electrons to the aromatic ring is less favored because the positive charge on nitrogen is next to the positively polarized carbonyl group. Resonance delocalization to the carbonyl oxygen is favored because of the electronegativity of oxygen. Since the nitrogen lone pair electrons are less available to the ring than in aniline, the reactivity of the ring toward electrophilic substitution decreases.
In the synthesis of acetanilide the hydrochloride salt of aniline is used in order to increase the solubility in water. The sodium acetate acts as a base and reacts with the HCl to produce acetic acid. Once the acetanilide product is no longer a hydrochloride salt, its solubility in water is decreased and it crystalises out. The main byproducts are sodium chloride and acetic acid which remain soluble in the water and are removed when the crude product is filtered off.
There is no any such difference between Aniline point and mixed Aniline point . . . . .
The chemical fomula of aniline is C6H7N.
An aniline is an aromatic amine, synthesized by the reduction of nitrobenzene.