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Starch is a very rich source of energy, in fact it is the plant's main way of storing energy. Potatoes are a great example- The green plant above ground photosynthesises constantly to pump energy into the underground vegetable where it is stored as starch.
Eating green vegetables, however, tend to have a much lower percentage of starch in their composition, and more complex carbohydrates which are more slowly digested by the body (low GI). Some, such as cellulose, may even may indigestible, with added perks like adding bulk to the faeces and lowering cholesterol.
Basically, starch is an energy-rich, basic and easily digestible molecule; whilst green vegetables are a source of many different nutrients, including more complex carbohydrates which are slowly or not digested (less energy; more diverse nutrients).

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Q: Why should people who are trying to lose weight cut back on their intake of starch but increase their intake of green vegetables?
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