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Q: Why silver nitrate reacts with chloride ions before chromate ions in Mohr's method?
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What are the limits for determination of chloride by the Mohr method?

1- done only in neutral medium. 2- all the cations which give insolublld be chromate must be absent or removed before titration. 3-titration of Ag+ with Cl- is not feasible. 4- not suitable for I- and SCN-


What any other method that can analyze chloride ion in seawater?

- Potentiometric titration with silver nitrate (AgNO3) - Titration (manual) with silver nitrate (AgNO3) or mercuric thiocyanate - Chronopotentiometry - Using ISE (Ion Selective Electrode) for Cl-


Why is blank titration necessary in the mohr method?

AS silver ions first react with Cloride ions in the sample(equivalence point) and when all the chloride ions are consumed we have to add more silver nitrate solution to increase its concentration to a level where it can precipitate chromate ions as silver chromate precipites (reddish brown ppts) this is the end point . so remove this error of equivalence point detection we take the same volume of indicator (chromate solution) in a flask labelled blank and add water into this flask (the same volume as that of sample solution) and then titrate this blank labelled flask with standard silver nitrate solution and note the volume of titrant consumed (blank volume),then calculations for real equivalence point can be made as: equivalence point=(end point)-(blank volume)


Why is back titration required in the volhard method?

This method uses a back titration with potassium thiocyanate to determine the concentration of chloride ions in a solution.Before the titration an excess volume of a standardized silver nitrate solution is added to the solution containing chloride ions, forming a precipitate of silver chloride (AgCl). The term 'excess' is used as the moles of silver nitrate added are known to exceed the moles of sodium chloride present in the sample so that all the chloride ions present will react.Ag+ + Cl- AgCl(s) (Ksp = 1.70 × 10−10)Excess WhiteExcess of Ag+ is back titrated with SCN-.


What are silver salts?

Examples: silver chloride, silver fluoride, silver iodide, silver bromide, silver astatide, silver sulfide, silver nitrate etc. For silver halogenides a method of preparation is the reaction between silver nitrate and a salt containing the halogen.


Why is the titration method suitable for the preparation of potassium nitrate?

bcz titration is da worst method


Speration method for sodium chloride solution and sodium chloride?

if u have sodium chloride solution just heat it..water will get evaporated leaving only sodium chloride


Which method to separate aqueous barium nitrate and aqueous sodium sulphate?

chromatography?


What method could be used to separate a mixture of barium sulphate and ammonium chloride and lead chloride?

none


What is the formula of potassium chloride by crisscross method?

K+ and Cl- react to form KCl (potassium chloride)


What is the separation technique for Silver chloride and sodium trioxonitrate?

Silver chloride is insoluble in water; filtration is a simple method.


How do you separate a mixture of sodium chloride and aluminium filings?

which method will be used to separate sodium chloride and aluminium particals