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What are the limits for determination of chloride by the Mohr method?
Wiki User
∙ 11y ago
1- done only in neutral medium.
2- all the cations which give insolublld be chromate must be absent or removed before titration.
3-titration of Ag+ with Cl- is not feasible.
4- not suitable for I- and SCN-
Wiki User
∙ 11y ago
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Can chloride and bromide simultaneously determine by Mohr method?
I want to assmue the the readers of this answer have know the details theory and calculations about Mohr method if not u can refer to Any analytical text for reference. Well, Bromide and Chloride can not be determine simultaneously in a sample using Mohr method , the reason be that the indicator use for each of them is different. and there will be problem in the procedure if ones try to determine both simultaneously. To determine Chloride Ion, Ammonium or Potassium Thiocynate is used as indicator and the sample must be neutral or slightly acidic. while Eosin indicator is use for the determination of Bromide Ion and the same neutral solution is prefer for this purpose, the solution must be adjusted to neutral either by adding small amount of Nitric acid or by adding small amount of carbonate as the case maybe. But, in the determination of each of them Silver Nitrate is use for the titration of both and this is the similarity they shared and the experimental procedure is quite the same. Olajire Mojeed
How can you test the percent purity of potassium chlorate?
by mohr's method
Why is it impossible to determine iodide ion by Mohr method?
I may be off, but it has something to do with thermodynamics. The silver reacts well with chlorine and bromide, but when it comes to iodide, i would guess that the dG is too low leaving the iodide in solution. Also, if you look at the solubility of silver iodide, it is VERY high in water which doesn't give you the chance to create the precipitate needed for use in the Mohr method. Silver Chloride - white precipitate Silver Bromide - ? precipitate. Silver Chromate - red good luck.
What is the hardness of rhyolite?
depends a rock made from lava is an igneous rock.
What is principle of potassium dichromate in COD estimation?
The titer volume of the sample gives the volume of Ferrous Ammonium Sulphate required to react with the excess potassium dichromate in the solution. Similarly, the titer volume for the blank (distilled water) gives the volume of Ferrous Ammonium Sulphate required to react with the excess potassium dichromate in the blank. The equation for the titration can be expressed as: Cr2O72 -- + FeSO4 (NH4)2SO4 = Cr+ + NH4+ + Fe 3+ From above equation it can be seen that one molecule of dichromate corresponds to one molecule of Mohr's salt. Thus, the difference in volume of excess K2Cr2O7 reacting with Mohr's solution can be calculated from the expression: = (Original vol. K2Cr2O7 -- vol. of K2Cr2O7 used for oxidation) solution - (Original vol. K2Cr2O7 -- vol. of K2Cr2O7 used for oxidation) blank = (Vol. of K2Cr2O7 used for oxidation) blank - Vol. of K2Cr2O7 used for oxidation) solution Hence, the difference in the titer volume for the solution and the blank is used to find out the Chemical Oxygen Demand directly.
Can chloride and bromide simultaneously determine by Mohr method?
I want to assmue the the readers of this answer have know the details theory and calculations about Mohr method if not u can refer to Any analytical text for reference. Well, Bromide and Chloride can not be determine simultaneously in a sample using Mohr method , the reason be that the indicator use for each of them is different. and there will be problem in the procedure if ones try to determine both simultaneously. To determine Chloride Ion, Ammonium or Potassium Thiocynate is used as indicator and the sample must be neutral or slightly acidic. while Eosin indicator is use for the determination of Bromide Ion and the same neutral solution is prefer for this purpose, the solution must be adjusted to neutral either by adding small amount of Nitric acid or by adding small amount of carbonate as the case maybe. But, in the determination of each of them Silver Nitrate is use for the titration of both and this is the similarity they shared and the experimental procedure is quite the same. Olajire Mojeed
Why mohr method is better than volhard method?
because mohar method gives the accurate result
How can you test the percent purity of potassium chlorate?
by mohr's method
What has the author Charles Lauren Mohr written?
Charles Lauren Mohr has written: 'An experimental determination of the dynamic physical constants of wood' -- subject(s): Compressed Wood, Wood, Compressed
Why is it impossible to determine iodide ion by Mohr method?
I may be off, but it has something to do with thermodynamics. The silver reacts well with chlorine and bromide, but when it comes to iodide, i would guess that the dG is too low leaving the iodide in solution. Also, if you look at the solubility of silver iodide, it is VERY high in water which doesn't give you the chance to create the precipitate needed for use in the Mohr method. Silver Chloride - white precipitate Silver Bromide - ? precipitate. Silver Chromate - red good luck.
What is a mohr method?
Mohr method is a Precipitation titrations method which is the concentration of an unknown substance in solution is determined by adding measured amount of a standard solution such as AgNO3 that react with unknown samples to determine CL, Br in Solid and solutions samples . NaCL + AgNO3 =====> AgCL + NaNO3. Br- + Ag NO3=====> AgBr + NO3- Then the concentration of the unkown can be calculated using the stoichiometry of the recation and the number of moles of standard solution needed to reach the End point. The mohr method uses chromate CrO4 2- ion as an indicator . By Known the stoichiometry and moles consumed at end point,we can determine the mount of chloride in an unknown samples. Saeed Yousef AL-Soumali
Why the brown colour appear and disappear at mohr method?
because the japs attacked pearl harbor and the dropping of the atomic bomb caused radiation poisoning, therefore causing the brown color, not colour to appear and disappear at mohr method, whatever that is.
How do you determine percentage purity of a salt by Mohr method?
Stop being a buttpirate and ask a real question... buttpirate!
What is the birth name of Hal Mohr?
Hal Mohr's birth name is Harold Leon Mohr.
What is the birth name of Jay Mohr?
Jay Mohr's birth name is Jon Ferguson Mohr.
Where can you buy Mohr salt?
At the Mohr Salt shop.
Why Mohr salt is called Mohr?
Mohr salt is (NH4)2Fe(SO4)2·6H2O. This name was attributed in the honor of the German chemist Karl Fiedrich Mohr.
