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I may be off, but it has something to do with thermodynamics. The silver reacts well with chlorine and bromide, but when it comes to iodide, i would guess that the dG is too low leaving the iodide in solution.
Also, if you look at the solubility of silver iodide, it is VERY high in water which doesn't give you the chance to create the precipitate needed for use in the Mohr method.
Silver Chloride - white precipitate
Silver Bromide - ? precipitate.
Silver Chromate - red
good luck.
What else can I help you with?
Can chloride and bromide simultaneously determine by Mohr method?
I want to assmue the the readers of this answer have know the details theory and calculations about Mohr method if not u can refer to Any analytical text for reference. Well, Bromide and Chloride can not be determine simultaneously in a sample using Mohr method , the reason be that the indicator use for each of them is different. and there will be problem in the procedure if ones try to determine both simultaneously. To determine Chloride Ion, Ammonium or Potassium Thiocynate is used as indicator and the sample must be neutral or slightly acidic. while Eosin indicator is use for the determination of Bromide Ion and the same neutral solution is prefer for this purpose, the solution must be adjusted to neutral either by adding small amount of Nitric acid or by adding small amount of carbonate as the case maybe. But, in the determination of each of them Silver Nitrate is use for the titration of both and this is the similarity they shared and the experimental procedure is quite the same. Olajire Mojeed
What are the limits for determination of chloride by the Mohr method?
1- done only in neutral medium. 2- all the cations which give insolublld be chromate must be absent or removed before titration. 3-titration of Ag+ with Cl- is not feasible. 4- not suitable for I- and SCN-
How can you test the percent purity of potassium chlorate?
To test the percent purity of potassium chlorate, you can perform a titration with a known concentration of a reducing agent, such as iron(II) sulfate, and determine the amount of reducing agent needed to completely react with the potassium chlorate. From the titration results, you can calculate the purity of the potassium chlorate by comparing the actual amount of potassium chlorate in the sample to the theoretical amount that should be present based on the reaction stoichiometry.
What is the hardness of rhyolite?
depends a rock made from lava is an igneous rock.
What is principle of potassium dichromate in COD estimation?
The titer volume of the sample gives the volume of Ferrous Ammonium Sulphate required to react with the excess potassium dichromate in the solution. Similarly, the titer volume for the blank (distilled water) gives the volume of Ferrous Ammonium Sulphate required to react with the excess potassium dichromate in the blank. The equation for the titration can be expressed as: Cr2O72 -- + FeSO4 (NH4)2SO4 = Cr+ + NH4+ + Fe 3+ From above equation it can be seen that one molecule of dichromate corresponds to one molecule of Mohr's salt. Thus, the difference in volume of excess K2Cr2O7 reacting with Mohr's solution can be calculated from the expression: = (Original vol. K2Cr2O7 -- vol. of K2Cr2O7 used for oxidation) solution - (Original vol. K2Cr2O7 -- vol. of K2Cr2O7 used for oxidation) blank = (Vol. of K2Cr2O7 used for oxidation) blank - Vol. of K2Cr2O7 used for oxidation) solution Hence, the difference in the titer volume for the solution and the blank is used to find out the Chemical Oxygen Demand directly.
Why is not possible to determine iodide by mohr titration?
Iodide cannot be determined by Mohr titration because it does not form a precipitate with silver nitrate. Mohr titration relies on the formation of a colored precipitate to indicate the end point, which is not observed in the case of iodide ions. Other methods, such as iodometric titration or spectrophotometry, are used to determine iodide ions quantitatively.
How do you determine percentage purity of a salt by Mohr method?
Stop being a buttpirate and ask a real question... buttpirate!
What is the difference between volhard and mohr methods?
The Volhard method is a titration method used to determine the concentration of halide ions in a solution using silver nitrate and potassium chromate as indicators. The Mohr method, on the other hand, is also a titration method used to determine the chloride ions concentration in a solution using silver nitrate and potassium chromate indicators. The key difference lies in the end point detection: Volhard method involves the use of a ferric alum indicator that forms a red-brown precipitate, while the Mohr method involves the formation of a red-brown silver chromate precipitate.
Why we used mohr method in neutralization solution?
The Mohr method is used in neutralization solutions to determine the concentration of chloride ions or substances that can be precipitated as silver chloride. By titrating the solution with a standardized silver nitrate solution using a chromate indicator, the endpoint is reached when all chloride ions have reacted to form a white precipitate. This method allows for accurate determination of chloride concentration in solution.
What is a mohr method?
Mohr method is a Precipitation titrations method which is the concentration of an unknown substance in solution is determined by adding measured amount of a standard solution such as AgNO3 that react with unknown samples to determine CL, Br in Solid and solutions samples . NaCL + AgNO3 =====> AgCL + NaNO3. Br- + Ag NO3=====> AgBr + NO3- Then the concentration of the unkown can be calculated using the stoichiometry of the recation and the number of moles of standard solution needed to reach the End point. The mohr method uses chromate CrO4 2- ion as an indicator . By Known the stoichiometry and moles consumed at end point,we can determine the mount of chloride in an unknown samples. Saeed Yousef AL-Soumali
Why mohr method is better than volhard method?
The Mohr method is typically preferred over the Volhard method for chloride titrations because it does not require a silver nitrate standard solution, making it more cost-effective and simpler to execute. Additionally, the Mohr method is more precise as it allows for a direct endpoint determination based on the formation of a specific silver chloride precipitate.
Can chloride and bromide simultaneously determine by Mohr method?
I want to assmue the the readers of this answer have know the details theory and calculations about Mohr method if not u can refer to Any analytical text for reference. Well, Bromide and Chloride can not be determine simultaneously in a sample using Mohr method , the reason be that the indicator use for each of them is different. and there will be problem in the procedure if ones try to determine both simultaneously. To determine Chloride Ion, Ammonium or Potassium Thiocynate is used as indicator and the sample must be neutral or slightly acidic. while Eosin indicator is use for the determination of Bromide Ion and the same neutral solution is prefer for this purpose, the solution must be adjusted to neutral either by adding small amount of Nitric acid or by adding small amount of carbonate as the case maybe. But, in the determination of each of them Silver Nitrate is use for the titration of both and this is the similarity they shared and the experimental procedure is quite the same. Olajire Mojeed
Why the brown colour appear and disappear at mohr method?
because the japs attacked pearl harbor and the dropping of the atomic bomb caused radiation poisoning, therefore causing the brown color, not colour to appear and disappear at mohr method, whatever that is.
Why indicator blank is used in mohr method?
An indicator blank is used in the Mohr method to account for any color changes that may occur due to impurities in the indicator itself. By measuring the blank, you can subtract this error from the titration result, ensuring accurate determination of the analyte concentration.
Why is mohr method suitable for use in neutral solutions only?
Well, honey, the Mohr method is suitable for use in neutral solutions only because it relies on a chromate indicator that changes color at a specific pH range. If the solution is too acidic or basic, the indicator won't work its magic properly. So, if you want accurate results, stick to neutral solutions with this method.
What is mohr metho in mechanics of material?
Mohr's method, or Mohr's circle, is a graphical representation used in mechanics of materials to analyze stress and strain on a material. It provides a visual way to determine the principal stresses, maximum shear stresses, and the orientation of these stresses in a two-dimensional stress system. By plotting the normal and shear stress components on a circle, engineers can easily visualize and compute the effects of different loading conditions on materials. This technique is particularly useful in determining failure criteria and material behavior under complex loading scenarios.
What is the birth name of Hal Mohr?
Hal Mohr's birth name is Harold Leon Mohr.
