0
Iodide cannot be determined by Mohr titration because it does not form a precipitate with silver nitrate. Mohr titration relies on the formation of a colored precipitate to indicate the end point, which is not observed in the case of iodide ions. Other methods, such as iodometric titration or spectrophotometry, are used to determine iodide ions quantitatively.
What else can I help you with?
What is the use of ferroin indicator in redox titration of Mohr's salt?
Ferroin indicator is used in the redox titration of Mohr's salt as it changes color when the Fe2+ ions are completely oxidized to Fe3+ ions. This color change helps in determining the end point of the titration, where all the Mohr's salt has been oxidized and no more Fe2+ ions are present.
Why HCl is used in titration of mohr salt and potassium dichromate?
Hydrochloric acid (HCl) is used in the titration of Mohr's salt and potassium dichromate because it reacts with Mohr's salt to form ferric chloride and with potassium dichromate to form chromium chloride. These reactions result in the formation of a color change in the solution which allows for the end point of the titration to be easily detected.
Why Mohr salt is called Mohr?
Mohr salt is named after the German chemist Karl Friedrich Mohr, who first synthesized it in 1855. He discovered the compound's chemical composition and properties that are frequently used in analytical chemistry and titration methods.
What are the uses of Mohr's salt?
Mohr's salt is primarily used as a reducing agent in various chemical reactions, such as in the laboratory synthesis of ammonia. It is also used in analytical chemistry for titration purposes, particularly in the determination of chloride ions. Additionally, Mohr's salt is employed in the production of pigments and dyes.
Why in Mohrs method of titration pH is maintain as neutral?
In Mohr's method of titration, the pH is maintained as neutral in order to ensure that the indicator used in the titration changes color sharply at the equivalence point. This helps in accurately determining the end point of the titration, as the color change will be clearly visible when the reaction is complete. Maintaining a neutral pH also prevents any interference from acidic or basic impurities that could affect the accuracy of the titration.
What is the use of ferroin indicator in redox titration of Mohr's salt?
Ferroin indicator is used in the redox titration of Mohr's salt as it changes color when the Fe2+ ions are completely oxidized to Fe3+ ions. This color change helps in determining the end point of the titration, where all the Mohr's salt has been oxidized and no more Fe2+ ions are present.
Why is it impossible to determine iodide ion by Mohr method?
I may be off, but it has something to do with thermodynamics. The silver reacts well with chlorine and bromide, but when it comes to iodide, i would guess that the dG is too low leaving the iodide in solution. Also, if you look at the solubility of silver iodide, it is VERY high in water which doesn't give you the chance to create the precipitate needed for use in the Mohr method. Silver Chloride - white precipitate Silver Bromide - ? precipitate. Silver Chromate - red good luck.
Why HCl is used in titration of mohr salt and potassium dichromate?
Hydrochloric acid (HCl) is used in the titration of Mohr's salt and potassium dichromate because it reacts with Mohr's salt to form ferric chloride and with potassium dichromate to form chromium chloride. These reactions result in the formation of a color change in the solution which allows for the end point of the titration to be easily detected.
What is the equivalent weight of mohr's salt in the titration of pottasium permanganate and mohr's salt?
The equivalent weight of Mohr's salt (ammonium iron(II) sulfate) is the molecular weight divided by the total positive charge of the cation(s) that are being titrated. In the titration of potassium permanganate with Mohr's salt, the equivalent weight of Mohr's salt is 88 g/mol (molecular weight) divided by the total positive charge of the cation(s) (in this case, 2), which equals 44 g/equivalent.
Why Mohr salt is called Mohr?
Mohr salt is named after the German chemist Karl Friedrich Mohr, who first synthesized it in 1855. He discovered the compound's chemical composition and properties that are frequently used in analytical chemistry and titration methods.
What is the difference between volhard and mohr methods?
The Volhard method is a titration method used to determine the concentration of halide ions in a solution using silver nitrate and potassium chromate as indicators. The Mohr method, on the other hand, is also a titration method used to determine the chloride ions concentration in a solution using silver nitrate and potassium chromate indicators. The key difference lies in the end point detection: Volhard method involves the use of a ferric alum indicator that forms a red-brown precipitate, while the Mohr method involves the formation of a red-brown silver chromate precipitate.
Why we add conc sulphuric acid in mohr salt in the titration of mohr salt against potassium dichromate?
For preparation of standard solution of Mohr salt {FeSO4.(NH4)2SO4.6H2O}, it's necessary to add dilute H2SO4 to prevent the Fe2+ ions of Mohr salt solution from undergoing oxidation (to Fe3+).
What are the uses of Mohr's salt?
Mohr's salt is primarily used as a reducing agent in various chemical reactions, such as in the laboratory synthesis of ammonia. It is also used in analytical chemistry for titration purposes, particularly in the determination of chloride ions. Additionally, Mohr's salt is employed in the production of pigments and dyes.
Why in Mohrs method of titration pH is maintain as neutral?
In Mohr's method of titration, the pH is maintained as neutral in order to ensure that the indicator used in the titration changes color sharply at the equivalence point. This helps in accurately determining the end point of the titration, as the color change will be clearly visible when the reaction is complete. Maintaining a neutral pH also prevents any interference from acidic or basic impurities that could affect the accuracy of the titration.
Why indicator blank is used in mohr method?
An indicator blank is used in the Mohr method to account for any color changes that may occur due to impurities in the indicator itself. By measuring the blank, you can subtract this error from the titration result, ensuring accurate determination of the analyte concentration.
Why does a colour change takes place while titrating mohr's salt against potassium dichromate?
From orange to (yellowish) green: It is a powerfull oxidant, used to titrate Fe2+ from Mohr's salt to the oxidised form Fe3+ by the following: Cr2O72−(aq) + 14H+ + 6e− → 2Cr3+(aq) + 7H2O
How can you test the percent purity of potassium chlorate?
To test the percent purity of potassium chlorate, you can perform a titration with a known concentration of a reducing agent, such as iron(II) sulfate, and determine the amount of reducing agent needed to completely react with the potassium chlorate. From the titration results, you can calculate the purity of the potassium chlorate by comparing the actual amount of potassium chlorate in the sample to the theoretical amount that should be present based on the reaction stoichiometry.
