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The experimental value may be either more or less than the theoretical value. Reasons for such differences:The theory may be incomplete, or a simplified version of reality. For example, you may use the ideal gas law; but real gases only behave APPROXIMATELY like the "ideal" gas.

In the experiment, there may be measurement errors. Or there may be other variables, which "contaminate" the result.

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Q: Why theory value is less than experiment value?
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