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Q: Why three different peaks are shown for benzene if all the three bonds are equivalent?
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Why is the gas phase spectrum of benzene different from the liquid phase?

In the gas phase, benzene molecules act independently. Benzene molecules in the liquid phase are closer together than in the gas phase. They interact with each other and alter the molar absorptivity values. This causes the sharp peaks of the gas phase spectrum to broaden. Collisional broadening is also a factor in the liquid phase as well.


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Adjacent carbons have more than one H atom which causes splitting of peaks in the spectrum. Multiple peaks corresponding to one or more magnetically equivalent atoms are multiplets


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