because sodium thiosulphate is unstable and iodine also so to maintain neutral medium we have to use sodiumcarboate
pink colour obtain on titration with potesium dicromate by using indicater n phanyl anthronilic
I also don't know
· In analytical chemistry, sodium thiosulphate is used for the determination of the strength of a given solution of iodine. · Sodium thiosulphate is preferred in iodometric analysis due to the fact that sodium thiosulphate is oxidized by iodine. It is also used to determine the strength of many oxidizing agents.
A thiosulfate titration is mostly carried out to determine the amount of iodine present in the solution. In these reactions, thiosulfate ion acts as the reducing agent. This types titrations are often called as 'iodometric titrations'.
In iodometry sodium thiosulphate is used because it is standardized by potassium dichromate and it is the best and relaible way to standardized sodium thiosulphate using iodometric titration. Infact sodium thiosulphate is also standardized by iodimetry. The difference between both of them is only of iodine. In iodometry iodine gas is liberated that will further react with sodium thiosulphate but in iodimetry standard solution of iodine is used.
E Mohr salt 392/1
Iodine value= (B-S)N x 12.69 ------------------- wt of sample where, B=titration of blank S= titration of sample N= normality of thiosulphate
to acidify the solution
(1) io3- + 5i- + 6h+ ® 3i2 + 3h2o (2) i2 + 2s2o32- ® 2i- + s4o62-
ki is added to liberate iodine gas . this liberated iodine gas was then titrated with sodium thiosulphate to give a permanent white precipitate. this white precipitate indicates the endpoint of the titration..
KI + CH3COOH --> HI + CH3COO-K+ ROOH + 2HI --> ROH + H2O + I2 TITRATION WITH SODIUM THIOSULPHATE TO DERIVE THE PEROXIDE VALUE 2NA2S2O3 + I2 (PURPLE) --> NA2S4O6 + NaI (COLOURLESS)
types of conductometric titration: acid base titration complexometric titration replacement titration redox titration precipitation titration