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I presume that we are here talking about a silicon semiconductor. The point of using a group 3 or a group 5 element is to use something that does not interfere too much with the crystal structure of silicon, but that has an extra electron for n-type doping, or absence of an electron for p-type doping. Thus for p-type doping we would use aluminium or gallium or scandium, because each of these has only 3 valence electrons instead of 4, while for n-type doping we would use phosphorus or arsenic or antimony, because these are elements with 5 valence electrons.

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Q: Why you only use 5th or 3rd group element for doping?
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