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Yes, but such words are quite uncommon. The only two examples I can come up with are "ylem" (pronounced "EE-lem", meaning the primordial substance of the universe) and "ylang-ylang" (pronounced "EE-lang-EE-lang", a fragrant tropical tree).

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Q: Y or w can be a vowel but is it possible that these are located at the start of a word thus requiring article an?
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