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No. Underglazes are colored clays that are applied to unfired clay and then covered with transparent glazes to be fired. They are fired at the same temperature at which both the glaze and the clay mature. Overglazes are applied over glaze, as the name implies. They are painted on glazed, fired items which are then refired at a much lower temperature. If overglazes are used during underglazing, they will probably burn out because the temperature is too high.

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Q: Can overglaze paint in ceramics be used during underglazing?
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