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I don't know for sure, but I have the same issue (2004 Endeavor LS). I have asked a mechanic this and the only answer i got was that it could be an exhaust leak. I haven't actually got it looked at, have you found out anything new?

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Q: On your 04 Mitsubishi endeavor when the engine is cold and you turn the car on the engine makes a rough knoking noisebut when you turn it off and back on it starts up just finewhat could be the cause?
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